| Identification | Back Directory | [Name]
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,2R)-(-)-2-(dimethylamino)cyclohexyl]thiourea(R,R-TUC) | [CAS]
620960-26-1 | [Synonyms]
1-[3,5-Bis(trifluoroMethyl)phenyl]-3-[(1R,2R)
-2-(diMethylaMino)cyclohexyl]thiourea
Thiourea, N-[3,5-bis(trifluoroMethyl)phenyl]-N'-[(1R,2R)-2-(diMethylaMino)cyclohexyl]-
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,2R)-2-
(dimethylamino)cyclohexyl]thiourea,99%e.e.
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,2R)-(-)-2-(dimethylamino)cyclohexyl]thiourea(R,R-TUC)
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,2R)-(-)-2-(dimethylamino)cyclohexyl]
thiourea (R,R-TUC) | [Molecular Formula]
C17H21F6N3S | [MDL Number]
MFCD09834839 | [MOL File]
620960-26-1.mol | [Molecular Weight]
413.428 |
| Chemical Properties | Back Directory | [Melting point ]
87-88°C | [alpha ]
-42° (c 1.05, CHCl3) | [Boiling point ]
380.8±52.0 °C(Predicted) | [density ]
1.33±0.1 g/cm3(Predicted) | [form ]
Powder | [pka]
11.76±0.70(Predicted) | [color ]
white |
| Questions And Answer | Back Directory | [Reaction]
- Thiourea catalyst used in the enantio and diastereoselective Michael addition of malonates and ketoesters to nitroolefins.
- Catalyst used in the enantioselective hydrazination of 1,3-dicarbonyl compounds.
- Catalyst used for the dynamic resolution of azalactones.
- Catalyst used in Michael-Aldol reaction of 2-mercaptobenzaldehyde with α,β-unsaturated oxazolidinone.
- Catalyst for enantioselective synthesis of flavanones and chromanones.
- Catalyst for the asymmetric Neber Reaction.
- Catalyst for the three component synthesis of 2,6-diazabicyclo[2.2.2]octanones.
|
|
|