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ChemicalBook--->CAS DataBase List--->57420-46-9

57420-46-9

57420-46-9 Structure

57420-46-9 Structure
IdentificationBack Directory
[Name]

8-O-acetyl shanzhiside methyl ester
[CAS]

57420-46-9
[Synonyms]

ND01
Barlerin
UMbroside
8-O-Acetyl shanzhiside methyl
8-Acetylshanzhiside Methyl ester
O-Acetyl Shanzhiside Methyl Ester, 8-
8-O-Acetyl shanzhiside methyl ester, >98%
8-O-Acetyl shanzhiside methyl ester, 98%, from Lamiophlomis rotata (Benth. ex Hook.f.) Kud
1α-(β-D-Glucopyranosyloxy)-7α-acetoxy-5α-hydroxy-7-methyl-1,4aα,5,6,7,7aα-hexahydrocyclopenta[c]pyran-4-carboxylic acid methyl ester
7α-Acetoxy-1α-(β-D-glucopyranosyloxy)-1,4aα,5,6,7,7aα-hexahydro-5α-hydroxy-7-methylcyclopenta[c]pyran-4-carboxylic acid methyl ester
(1S)-1α-(β-D-Glucopyranosyloxy)-5α-hydroxy-7α-acetoxy-7-methyl-1,4aα,5,6,7,7aα-hexahydrocyclopenta[c]pyran-4-carboxylic acid methyl ester
methyl (1S,4aS,5R,7S,7aS)-7-(acetyloxy)-1-(beta-D-glucopyranosyloxy)-5-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylate
Cyclopenta[c]pyran-4-carboxylic acid, 7-(acetyloxy)-1-(β-D-glucopyranosyloxy)-1,4a,5,6,7,7a-hexahydro-5-hydroxy-7-methyl-, methyl ester, (1S,4aS,5R,7S,7aS)-
methyl (1S,4aS,5R,7S,7aS)-7-acetyloxy-5-hydroxy-7-methyl-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4a,5,6,7a-tetrahydro-1H-cyclopenta[c]pyran-4-carboxylate
[Molecular Formula]

C19H28O12
[MDL Number]

MFCD15071141
[MOL File]

57420-46-9.mol
[Molecular Weight]

448.42
Chemical PropertiesBack Directory
[Boiling point ]

634.2±55.0 °C(Predicted)
[density ]

1.52
[storage temp. ]

-20°C
[solubility ]

Soluble in methan
[form ]

powder
[pka]

12.80±0.70(Predicted)
[color ]

White
Safety DataBack Directory
[Safety Statements ]

24/25
[HS Code ]

29389090
Hazard InformationBack Directory
[Chemical Properties]

Off-white crystalline powder, easily soluble in methanol and ethanol, derived from unique flavor.
[Uses]

8-O-acetyl shanzhiside methyl ester can be used for content determination, identification and pharmacological experiments, etc. It can activate congestion, relieve pain and stop bleeding.
[in vitro]

Treatment of SH-SY5Y cells with 8-O-Acetyl shanzhiside methyl ester blocks TNF-α-induced nuclear transcription factor κB (NF-κB) activation and decreases high-mobility group box-1 ( HMGB-1) expression . Treatment of H9c2 cells with it 9 μM blocks TNF-α-induced NF-κB phosphorylation by blocking High-mobility group box1 (HMGB1) expression.
[in vivo]

8-O-Acetyl shanzhiside methyl ester significantly promotes angiogenesis in the ischaemic brain and improves functional outcome after stroke. It also significantly increases vascularization compared with vehicle treatment. 8-O-Acetyl shanzhiside methyl ester significantly shortens capillary blood clotting time and reduces blood loss volume, but does not influence mice activated partial thromboplastin time , prothrombin time or thrombin time.
Spectrum DetailBack Directory
[Spectrum Detail]

8-O-acetyl shanzhiside methyl ester(57420-46-9)1HNMR
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