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ChemicalBook--->CAS DataBase List--->54327-10-5

54327-10-5

54327-10-5 Structure

54327-10-5 Structure
IdentificationBack Directory
[Name]

METHYL GREEN
[CAS]

54327-10-5
[Synonyms]

CI 42585
PARIS GREEN
CI NO 42590
CI NO 42585
LIGHT GREEN
DOUBLE GREEN
BASIC BLUE 20
DOUBLE GREEN SF
CI BASIC BLUE 20
1%aqueoussolution
Brilliant Blue B
CUPRIC ACETOARSENITE
GLYCEROL /METHYL GREEN
COPPER (II) ACETOARSENITE
PARIS GREEN C.I. NO. 42585
MethylGreen1%AqueousSolution
HEPTAMETHYL-P-ROSANILINE CHLORIDE
METHYL GREEN ZINC CHLORIDE DOUBLE SALT
[Molecular Formula]

C26H33Cl2N3
[MDL Number]

MFCD00011879
[MOL File]

54327-10-5.mol
[Molecular Weight]

458.47
Chemical PropertiesBack Directory
[Melting point ]

>300°C
[solubility ]

Solubility Soluble in water, ethanol; insoluble in xylene
[form ]

powder
[color ]

Green crystalline
[PH Range]

Yellow (0.1) to greenish-blue (2.3)
[λmax]

635nm, 420nm
[Major Application]

Liquid crystal display device, photography, recording materials, inks, cosmetics, DNA staining, cancer detection
Hazard InformationBack Directory
[Definition]

ChEBI: Methyl green is an iminium salt composed of (4-{[4-(dimethylamino)phenyl][4-(trimethylazaniumyl)phenyl]methylidene}cyclohexa-2,5-dien-1-ylidene)(dimethyl)ammonium and chloride ions in a 1:2 ratio. A histological dye used to demonstrate nucleic acids by the Unna-Pappenheim stain, in conjunction with Pyronin Y. It has a role as a fluorochrome and a histological dye. It is an organic chloride salt, an iminium salt and a quaternary ammonium salt. It contains a methyl green(2+).
[Synthesis]

Cupric oxide is heated with 8% acetic acid, As2O3 is added, and the mixture is refluxed for two hours. The product is allowed to cool for half an hour, filtered, washed and dried.Alternate method: Dilute acetic acid is allowed to react with an excess of freshly precipitated Cu(OH)2 and the product is separated by filtration. Dilute acetic acid is added to a solution of As2O3 in boiling NaOH until the color of phenolphthalein disappears. The hot solutions are mixed (mole ratio of CuO:As2O3 = 4:3) and allowed to stand for several days [S. Avery, J. Amer. Chem. Soc. 28, 1159 (1906)].
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