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ChemicalBook--->CAS DataBase List--->521272-85-5

521272-85-5

521272-85-5 Structure

521272-85-5 Structure
IdentificationBack Directory
[Name]

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh
[CAS]

521272-85-5
[Synonyms]

(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(R,R)-NORPHOS-Rh
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-
cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (R,R)-NORPHOS-Rh
[Molecular Formula]

C31H28P2.C8H12.BF4.Rh
[MDL Number]

MFCD09839137
[MOL File]

521272-85-5.mol
[Molecular Weight]

760.406
Chemical PropertiesBack Directory
[form ]

Powder
[color ]

red-orange
[Sensitive ]

air sensitive
[CAS DataBase Reference]

521272-85-5
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H335-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Questions And AnswerBack Directory
[Reactions]

Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.  Reactions of 521272-85-5
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