| Identification | Back Directory | [Name]
(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL | [CAS]
42177-25-3 | [Synonyms]
(R)-(+)-α
(1R)-1-(1-naphthyl)ethan
(1R)-1-(1-naphthyl)ethanol
(R)-(+)-1-(1-NAPHTHYL)ETHANOL
R-(-)-1-(1-Napthalenyl)ethanol
R-(-)-1-(1-naphthalenyl)ethanol
(r)-(+)-α-methyl-1-naphthalenemethanol
1-Naphthalenemethanol, α-methyl-, (αR)-
(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL | [Molecular Formula]
C12H12O | [MDL Number]
MFCD00077830 | [MOL File]
42177-25-3.mol | [Molecular Weight]
172.22 |
| Chemical Properties | Back Directory | [Melting point ]
47-49 °C(lit.)
| [alpha ]
78 º (C=1 IN MEOH) | [Boiling point ]
316.0±11.0 °C(Predicted) | [density ]
1.113±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [pka]
14.29±0.20(Predicted) |
| Hazard Information | Back Directory | [Chemical Properties]
White solid | [Uses]
(R)?-?1-?(Naphthalen-?1-?yl)?ethanol is a coupling reagent used in the synthesis of ferrocene aminophosphoxazoline ligands. | [Purification Methods]
Purify the alcohol by recrystallisation from Et2O/pet ether, Et2O, hexane [Balfe et al. J Chem Soc 797 1946, IR, NMR: Theisen & Heathcock J Org Chem 53 2374 1988, see also Fredga et al. Acta Chem Scand 11 1609 1957]. The RS-alcohol [57605-95-5] has m 63-65o, 65-66o from hexane. [Beilstein 6 III 3034, 6 IV 4346.] |
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