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ChemicalBook--->CAS DataBase List--->373650-12-5

373650-12-5

373650-12-5 Structure

373650-12-5 Structure
IdentificationBack Directory
[Name]

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
[CAS]

373650-12-5
[Synonyms]

(S)-Ru(OAc)2(SEGPHOS)
(S)-Ru(OAc)2(SEGPHOS(R))
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos]
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
[Molecular Formula]

C38H28O4P2.C4H6O4Ru
[MDL Number]

MFCD09753024
[MOL File]

373650-12-5.mol
[Molecular Weight]

829.741
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[form ]

solid
[color ]

yellow to black
[Sensitive ]

air sensitive
Questions And AnswerBack Directory
[Reaction]

  1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination.
  2. Asymmetric hydrogenation of substituted allyl alcohols.
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