Identification | Back Directory | [Name]
Boron trifluoride dimethanol complex | [CAS]
2802-68-8 | [Synonyms]
13-15%BF3solutioninmethanol Boron trifluoride metanol complex Boron trifluoride dimethanol complex Boron trifluoride-methanol in methanol Threeboron trifluorideMethanol coMplex Methanol-boron trifluoride complex (2:1) Boron trifluoride-methanol-complex solution Boron trifluoride methanol complex, BF_3 ca 50% BORON TRIFLUORIDE DIMETHANOL COMPLEX, 50-52 WT% BF3 Hydrogen trifluoromethoxyborate, compound with methanol Boron trifluoride diMethanol coMplex, 50-52 wt% BF3 50GR Boron trifluoride diMethanol coMplex, 50-52 wt% BF3 250GR Boron trifluoride-dimethanol complex w/w boron trifluoride Hydrogentrifluoromethoxyborate(1-),compoundwithmethanol(1:1) Boron trifluoride-methanol-complex solution 13-15% BF3 basis Boron trifluoride-dimethanol complex, 50-52% w/w boron trifluoride Boron trifluoride-methanol in methanol (ca. 50% w/w boron trifluoride) borate(1-),trifluoromethoxy-,(beta-4)-,hydrogen,compd.withmethanol(1:1) Borate(1-), trifluoromethoxy-, (T-4)-, hydrogen, compd. with methanol (1:1) | [EINECS(EC#)]
220-543-9 | [Molecular Formula]
C2 H8 B F3 O2 | [MDL Number]
MFCD00071635 | [MOL File]
2802-68-8.mol | [Molecular Weight]
131.89 |
Chemical Properties | Back Directory | [Appearance]
clear colourless to slightly yellow liquid | [Melting point ]
-20 °C | [Boiling point ]
58-60°C 4mm | [density ]
1,222 g/cm3 | [vapor pressure ]
11.6hPa at 20℃ | [refractive index ]
1.34 | [Fp ]
68°C | [storage temp. ]
Store below +30°C. | [form ]
clear liquid | [color ]
Colorless to Light orange to Yellow | [explosive limit]
5.5% (v/v) Methanol) | [Water Solubility ]
HYDROLYSIS | [Sensitive ]
Moisture Sensitive | [Merck ]
14,1349 | [BRN ]
3693581 | [Exposure limits]
ACGIH: TWA 2.5 mg/m3; Ceiling 1 ppm OSHA: Ceiling 1 ppm(3 mg/m3) NIOSH: IDLH 25 ppm; Ceiling 1 ppm(3 mg/m3) | [EPA Substance Registry System]
Borate(1-), trifluoromethoxy-, (T-4)-, hydrogen, compd. with methanol (1:1)(2802-68-8) |
Hazard Information | Back Directory | [Chemical Properties]
clear colourless to slightly yellow liquid | [Uses]
Boron trifluoride-methanol complex solution can be used for the deprotection of acetylated amines of cyanine dyes to form products with free amino groups. It may be used for the conversion of sulfur-containing phosphoramidates to the corresponding phosphate methyl ester. | [Flammability and Explosibility]
Notclassified | [reaction suitability]
core: boron reagent type: Lewis acid reagent type: catalyst |
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