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IdentificationBack Directory
[Name]

9-BROMO-9-BORABICYCLO[3.3.1]NONANE
[Synonyms]

B-BROMO-9-BBN
beta-Bromo-9-bbn
B-Bromo-9-BBN solution
9-BROMO-9-BORABICYCLO[3.3.1]NONANE
B-Bromo-9-borabicyclo[3.3.1]nonane
9-Borabicyclo[3.3.1]nonane, 9-bromo-
B-BROMO-9-BBN 1.0M SOLUTION IN &
9-Bromo-9-borabicyclo[3.3.1]nonane solution
B-BROMO-9-BBN, 1.0M SOLUTION IN DICHLOROMETHANE
[MDL Number]

MFCD00074773
[MOL File]

22086-45-9.mol
Chemical PropertiesBack Directory
[Boiling point ]

54-59 °C(Press: 0.3-0.4 Torr)
[Fp ]

-17 °C
[solubility ]

sol pentane, CH2Cl2; dec ethers, alcohols
Safety DataBack Directory
[Symbol(GHS) ]


GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335-H336-H351-H373
[Precautionary statements ]

P261-P281-P305+P351+P338
[Safety Statements ]

16-26-36/37/39-45-36/37
[RIDADR ]

UN 2845 4.2/PG 1
Hazard InformationBack Directory
[Uses]

9-BROMO-9-BORABICYCLO[3.3.1]NONANE is a selective reagent for the cleavage of ethers and deoxygenation of sulfoxides; adds regioselectively and stereoselectively to terminal alkynes; undergoes conjugate addition to α,β-unsaturated ketones; converts vinyltins to vinylboranes.
[storage]

9-BROMO-9-BORABICYCLO[3.3.1]NONANE is pyrophoric and reacts violently with moisture and protic solvents. Individuals should thoroughly familiarize themselves with the special handling techniques required for such reagents prior to use. Use in a well-ventilated fume hood.
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