| Identification | Back Directory | [Name]
1-METHOXY-1,3-CYCLOHEXADIENE | [CAS]
2161-90-2 | [Synonyms]
2,3-DIHYDROANISOLE
1-METHOXY-1,3-CYCLOHEXADIENE
1-methoxycyclohexa-1,3-diene
1,3-Cyclohexadiene, 1-methoxy-
1,3-Cyclohexadien-1-yl methyl ether
1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%
1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole
1-Methoxy-1,3-cyclohexadiene technical grade, 65% | [EINECS(EC#)]
218-483-3 | [Molecular Formula]
C7H10O | [MDL Number]
MFCD00001533 | [MOL File]
2161-90-2.mol | [Molecular Weight]
110.15 |
| Chemical Properties | Back Directory | [Melting point ]
96-97 °C | [Boiling point ]
40 °C/15 mmHg (lit.) | [density ]
0.929 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.488(lit.) | [Fp ]
80 °F | [LogP]
1.790 (est) |
| Hazard Information | Back Directory | [Uses]
1-Methoxy-1,3-cyclohexadiene was used in the following studies:
- Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
- Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
- Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.
| [Synthesis Reference(s)]
Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X | [General Description]
1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative. |
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