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ChemicalBook--->CAS DataBase List--->205319-06-8

205319-06-8

205319-06-8 Structure

205319-06-8 Structure
IdentificationBack Directory
[Name]

Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
[CAS]

205319-06-8
[Synonyms]

Pd-117
bis(diphenylphosphinophenyl)etherpalladium(II)...
Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II)
Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)
cis-[Bis[2-(diphenylphosphino)phenyl] ether]dichloropalladium
Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II), Pd 14.8%
[Molecular Formula]

C36H28Cl2OP2Pd
[MDL Number]

MFCD09953446
[MOL File]

205319-06-8.mol
[Molecular Weight]

717.9
Chemical PropertiesBack Directory
[Appearance]

light yellow powder
[Melting point ]

243-250°C
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

yellow
[Water Solubility ]

Insoluble in water.
[InChIKey]

VYOUBMJFTDMKRR-UHFFFAOYSA-L
[SMILES]

P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1OC1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
Hazard InformationBack Directory
[Chemical Properties]

light yellow powder
[Uses]

Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) is used as a catalyst for cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z,E dienes.
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

2843909000
Questions And AnswerBack Directory
[Reaction]

  1. Stereoretentive palladium-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.
  2. Highly selective reactions of unbiased alkenyl halides: Negishi-Plus couplings.
Reactions of 205319-06-8
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(diphenylphosphinophenyl)ether palladium (II) dichloride(205319-06-8)1HNMR
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