| Identification | Back Directory | [Name]
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) | [CAS]
199684-47-4 | [Synonyms]
(R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]
[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]
(R)-[(RuCl(BINAP))2(μ
-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R)
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II)
Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3]
DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3] | [Molecular Formula]
(CH3)2NH2+[C88H64Cl5P4Ru2]- | [MDL Number]
MFCD09753033 | [MOL File]
199684-47-4.mol | [Molecular Weight]
1674.89 |
| Questions And Answer | Back Directory | [Reaction]
- (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.
- Useful ligand in asymmetric Heck processes.
- Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
- Ligand employed in rhodium-catalyzed 1,4-additions to enones.
- Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
- Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.
- Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
- Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
- Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
- Ligand employed in palladium-catalyzed synthesis of chiral allenes.
- Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.
- Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
- Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.
- Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
- Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
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