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ChemicalBook--->CAS DataBase List--->19584-30-6

19584-30-6

19584-30-6 Structure

19584-30-6 Structure
IdentificationBack Directory
[Name]

TETRARHODIUM DODECACARBONYL
[CAS]

19584-30-6
[Synonyms]

Dodecacarbonyltetrar
DODECACARBONYLTETRARHODIUM
TETRARHODIUM DODECACARBONYL
DODECACARBONYLTETRARHODIUM (0)
Tetrarhodium dodecacarbonyl,98%
Tetrarhodiumdodecacarbonyl,min.98%
Tetrarhodium dodecacarbonyl, min. 98%
tri-mu-carbonylnonacarbonyl-tetrahedro-tetrarhodium
[EINECS(EC#)]

243-171-9
[Molecular Formula]

C12O12Rh4
[MDL Number]

MFCD00016310
[MOL File]

19584-30-6.mol
[Molecular Weight]

747.74
Chemical PropertiesBack Directory
[Appearance]

red to dark brown crystalline powder
[Melting point ]

150℃ [DOU83]
[density ]

2,52 g/cm3
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

reacts with H2O
[form ]

crystal
[color ]

dark red
[Specific Gravity]

2.52
[Sensitive ]

air sensitive, light sensitive, store cold
[InChIKey]

LVGLLYVYRZMJIN-UHFFFAOYSA-N
Hazard InformationBack Directory
[Chemical Properties]

red to dark brown crystalline powder
[Uses]

Dodecacarbonyltetrarhodium is used as a catalyst for hydrogenation, hydroformylation, silylformylation, hydroboration, aldol reactions.
[Preparation]

Dodecacarbonyltetrarhodium is prepared from Tetracarbonyl(di-μ-chloro)dirhodium.
[reaction suitability]

core: rhodium
reagent type: catalyst
[storage]

Dodecacarbonyltetrarhodium is air sensitive; should be handled under nitrogen or argon; water sensitive (decomposes to Rh6(CO)16 in the presence of water); heat sensitive; store in refrigerator under carbon monoxide. Use in a fume hood.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

36
[RIDADR ]

3089
[WGK Germany ]

3
[HazardClass ]

4.1
[PackingGroup ]

III
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