| Identification | Back Directory | [Name]
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) | [CAS]
19529-00-1 | [Synonyms]
Tetrakis(triphenylphosphine)ruthenium dihydride
Dihydridotetrakis(triphenylphosphine)ruthenium(Ⅱ)
TETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) HYDRIDE
dihydridotetrakis(triphenylphosphine)-ruthenium(I
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
Dihydrotetrakis(triphenylphosphine)ruthenium(II), 95%
Dihydridotetrakis(triphenylphosphine)ruthenium(II),97% | [Molecular Formula]
C72H62P4Ru | [MDL Number]
MFCD04126429 | [MOL File]
19529-00-1.mol | [Molecular Weight]
1152.23 |
| Chemical Properties | Back Directory | [Appearance]
ochre lustrous powder | [Melting point ]
181-183 °C(lit.)
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Slightly soluble in benzene, toluene, and THF. | [form ]
Lustrous Powder | [color ]
Ochre | [Sensitive ]
air sensitive |
| Hazard Information | Back Directory | [Chemical Properties]
ochre lustrous powder | [Uses]
Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation | [Synthesis]
The Preparative Method of Dihydridotetrakis(triphenylphosphine)ruthenium(II): prepared from Ruthenium(III) Chloride or ruthenium(III) acetylacetonate by reduction with Triethylaluminum in the presence of Triphenylphosphine in THF or benzene under nitrogen at room temperature. The complex can also be prepared by reacting Dichlorotris(triphenylphosphine)ruthenium(II) with Sodium Borohydride and triphenylphosphine. | [Purification Methods]
Dihydridotetrakis(triphenylphosphine)ruthenium(II) could be recrystallized from benzene, toluene, or THF.
| [Precautions]
Dihydridotetrakis(triphenylphosphine)ruthenium(II) is air and light-sensitive and should be stored under argon in the dark.
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| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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