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ChemicalBook--->CAS DataBase List--->18173-64-3

18173-64-3

18173-64-3 Structure

18173-64-3 Structure
IdentificationBack Directory
[Name]

TERT-BUTYLDIMETHYLSILANOL
[CAS]

18173-64-3
[Synonyms]

Butyldimethylsilanol
T-BUTYLDIMETHYLSILANOL
TERT-BUTYLDIMETHYLSILANOL
tert-ButyldiMethylsilanol 99%
tert-Butyldimethylhydroxysilane
ert-butyl-hydroxy-dimethylsilane
tert-Butyl-hydroxy-Dimethylsilane
tert-Butyldimethyl(hydroxy)silane
SIB1939.0 !! T-BUTYLDIMETHYLSILANOL
Silanol, (1,1-dimethylethyl)dimethyl-
Silanol, 1-(1,1-dimethylethyl)-1,1-dimethyl-
[Molecular Formula]

C6H16OSi
[MDL Number]

MFCD00010673
[MOL File]

18173-64-3.mol
[Molecular Weight]

132.28
Chemical PropertiesBack Directory
[Melting point ]

18 °C
[Boiling point ]

139 °C739 mm Hg(lit.)
[density ]

0.84 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.424(lit.)
[Fp ]

113 °F
[solubility ]

soluble in Benzene
[form ]

clear liquid
[pka]

15.37±0.53(Predicted)
[color ]

Colorless to Almost colorless
[Specific Gravity]

0.840
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

1732777
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

10-36/37/38
[Safety Statements ]

26-36
[RIDADR ]

UN 1987 3/PG 3
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

No
[HS Code ]

2931.90.9010
[HazardClass ]

3.2
[PackingGroup ]

III
Hazard InformationBack Directory
[Uses]

tert-Butyldimethylsilanol can be used as a silylating agent for the protection of hydroxyl groups via silylation. It is used:
  • For the preparation of α-chiral ether derivatives by catalytic asymmetric allylic substitution.
  • As an initiator for the polymerization of 1,2 benzenedicarboxaldehyde.
  • In the synthesis of enol silyl ethers.

Spectrum DetailBack Directory
[Spectrum Detail]

TERT-BUTYLDIMETHYLSILANOL(18173-64-3)1HNMR
TERT-BUTYLDIMETHYLSILANOL(18173-64-3)Raman
TERT-BUTYLDIMETHYLSILANOL(18173-64-3)IR
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