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ChemicalBook--->CAS DataBase List--->174810-09-4

174810-09-4

174810-09-4 Structure

174810-09-4 Structure
IdentificationBack Directory
[Name]

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
[CAS]

174810-09-4
[Synonyms]

(R,R)-TROST LIGAND(NAPHTHYL)
(R,R)-DACH-naphthyl Trost ligand
(R,R)-DACH-naphthyl Trost ligand 95%
N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%
1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
N,N'-(1R,2R)-Cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide]
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand
[Molecular Formula]

C52H44N2O2P2
[MDL Number]

MFCD02684551
[MOL File]

174810-09-4.mol
[Molecular Weight]

790.87
Chemical PropertiesBack Directory
[Appearance]

white to off-white powder
[Melting point ]

224-231 °C
[alpha ]

69o (C=1 IN METHANOL)
[form ]

Powder
[pka]

13.43±0.40(Predicted)
[color ]

off-white
[optical activity]

[α]20/D +69.0°, c = 1 in methanol
[InChIKey]

VXFKMKXTPXVEMU-AWSIMMLFSA-N
[CAS DataBase Reference]

174810-09-4
Hazard InformationBack Directory
[Chemical Properties]

white to off-white powder
[Uses]

Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[HS Code ]

2931499090
Questions And AnswerBack Directory
[Reactions]

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles. Reactions of 174810-09-4_1
Reactions of 174810-09-4_2
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