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ChemicalBook--->CAS DataBase List--->1746-81-2

1746-81-2

1746-81-2 Structure

1746-81-2 Structure
IdentificationBack Directory
[Name]

MONOLINURON
[CAS]

1746-81-2
[Synonyms]

ARESIN
Afesin
Arezin
Arezine
ARRESIN
hoe2747
Premalin
HOE 2747
Monorotox
Aresin(TM)
MONOLINURON
Monolinuron 0
Monolinuron-D6
3-(4-Chlorophenyl)
Monolinuron Standard
-1-methoxy-1-methylurea
monolinuron (bsi,iso,wssa)
Monolinuron @100 μg/mL in MeOH
Monolinuron 250mg [1746-81-2]
Linuron Impurity 3 (Monolinuron)
MONOLINURON PESTANAL (3-(4-CHLORO- PHENY
1-Methoxy-1-methyl-3-(4-chlorophenyl)urea
3-(4-CHLOROPHENYL)-1-METHOXY-1-METHYLUREA
3-(p-chlorophenyl)-1-methoxy-1-methyl-ure
n-(4-chlorophenyl)-n’-methoxy-n-methylurea
N'-(4-Chlorophenyl)-N-methoxy-N-methylurea
N-(4-Chlorophenyl)-N'-methoxy-N-methylurea
n’-(4-chlorophenyl)-n-methoxy-n-methyl-ure
N’-(4-chlorophenyl)-N-methoxy-N-methylurea
3-(p-Chlorophenyl)-1-methoxy-1-methyl urea
urea,3-(p-chlorophenyl)-1-methoxy-1-methyl-
Urea, 3-(p-chlorophenyl)-1-methoxy-1-methyl-
Urea,N'-(4-chlorophenyl)-N-Methoxy-N-Methyl-
3-(4-Chlorphenyl)-1-methoxy-1-methylharnstoff
UREA,3-(PARA-CHLOROPHENYL)-1-METHOXY-1-METHYL-
monolinuron (ISO) 3-(4-chlorophenyl)-1-methoxy-1-methylurea
[EINECS(EC#)]

217-129-5
[Molecular Formula]

C9H11ClN2O2
[MDL Number]

MFCD00055264
[MOL File]

1746-81-2.mol
[Molecular Weight]

214.65
Chemical PropertiesBack Directory
[Melting point ]

81.5℃
[density ]

1.3575 (rough estimate)
[refractive index ]

1.5790 (estimate)
[Fp ]

100 °C
[storage temp. ]

0-6°C
[form ]

neat
[pka]

12.80±0.70(Predicted)
[color ]

White to Light yellow to Light orange
[Water Solubility ]

0.58g/L(room temperature)
[BRN ]

2212523
[InChI]

InChI=1S/C9H11ClN2O2/c1-12(14-2)9(13)11-8-5-3-7(10)4-6-8/h3-6H,1-2H3,(H,11,13)
[InChIKey]

LKJPSUCKSLORMF-UHFFFAOYSA-N
[SMILES]

N(OC)(C)C(NC1=CC=C(Cl)C=C1)=O
[EPA Substance Registry System]

Monolinuron (1746-81-2)
Safety DataBack Directory
[Hazard Codes ]

Xn,N
[Risk Statements ]

22-48/22-50/53
[Safety Statements ]

22-60-61
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

YS6425000
[HS Code ]

29280000
[Safety Profile]

Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of Cland NOx.
[Hazardous Substances Data]

1746-81-2(Hazardous Substances Data)
Hazard InformationBack Directory
[Definition]

ChEBI: Monolinuron is a member of ureas.
[Reactions]

Nitrite or nitrate induced-photolysis of monolinuron (a phenyl urea herbicide) using the 300–450 nm light excitation gives rise to various photo-products. The direct photolysis of monolinuron proceeds via two main pathways yielding, respectively, 3-(4-chlorophenyl)-1-methylurea, which results from demethoxylation of the N-terminus substituted functional group and 3-(4-hydroxyphenyl)-1-methoxy-1-  methylurea obtained by photohydrolysis of the C-Cl bond[1].
Degradation pathways of monolinuron by direct and nitrite (or nitrate) induced photolysis. Specific photoproducts: circled numbers (direct); underlined numbers (induced):
MONOLINURON
[References]

[1] S. Nélieu. “Nitrite and nitrate induced photodegradation of monolinuron in aqueous solution.” Environmental Chemistry Letters 2 2 (2004): 83–87.
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