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ChemicalBook--->CAS DataBase List--->1702311-34-9

1702311-34-9

1702311-34-9 Structure

1702311-34-9 Structure
IdentificationBack Directory
[Name]

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
[CAS]

1702311-34-9
[Synonyms]

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3]
[Molecular Formula]

C45H65FeNO3P2PdS
[MDL Number]

MFCD27978424
[MOL File]

1702311-34-9.mol
[Molecular Weight]

925.288
Chemical PropertiesBack Directory
[Melting point ]

180-186 °C
[form ]

solid
[color ]

red-orange
[InChIKey]

VXSQFQJKYCLYAK-DHOIFHORSA-N
Questions And AnswerBack Directory
[Reaction]

Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides. Reactions of 1702311-34-9
Hazard InformationBack Directory
[General Description]

Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
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