| Identification | Back Directory | [Name]
TRIS(ACETONITRILE)TRICARBONYLTUNGESTEN(& | [CAS]
16800-47-8 | [Synonyms]
tris(acetonitrile)tungsten(0)
Tris(acetonitryl)tungsten tricarbonyl
tris(acetonitrile)tricarbonyl-tungste
Tricarbonyl tris(acetonitrile)tungsten
Tris(acetonitrile)tungsten tricarbonyl
TRIS(ACETONITRILE)TRICARBONYLTUNGESTEN(&
tris(acetonitrile)tricarbonyltungsten(0) | [EINECS(EC#)]
240-833-9 | [Molecular Formula]
C9H9N3O3W | [MDL Number]
MFCD00054393 | [MOL File]
16800-47-8.mol | [Molecular Weight]
391.03 |
| Hazard Information | Back Directory | [Uses]
Catalyst for allylic substitutions
Reactant for:
- Mixed disilyl-substituted cyclopentadiene derivatives
- Synthesis of catalytically active ansa compounds with cycloalkyl moieties
- Stepwise assembly of mixed metal dinuclear carbonyl complexes
- Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes
| [Preparation]
By refluxing Hexacarbonyltungsten in Acetonitrile in an inert atmosphere. Removal of solvent under an inert atmosphere yields tris(acetonitrile)tricarbonyltungsten. Solutions of the reagent can be prepared by photolysis of hexacarbonyltungsten in acetonitrile. | [reaction suitability]
core: tungsten
reagent type: catalyst | [storage]
Air and thermally sensitive; pyrophoric. Use in a fume hood. |
|
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