| Identification | Back Directory | [Name]
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE | [CAS]
164931-83-3 | [Synonyms]
(R,R)Jacbosen
(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan
(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride
（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride
Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- | [EINECS(EC#)]
605-379-1 | [Molecular Formula]
C36H52ClCrN2O2 | [MDL Number]
MFCD02684555 | [MOL File]
164931-83-3.mol | [Molecular Weight]
632.26 |
| Questions And Answer | Back Directory | [Reactions]
- Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
- Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
- Catalyst for copolymerization of CO2 and epoxides.
- Catalyst for enantioselective alkylation of tributyltin enolates.
- Enantioselective addition of Me2Zn to aldehydes.
- Enantioselective intramolecular addition of tertiary enamides to ketones.
- Asymmetric iodocyclization.
- Catalytic intermolecular linear allylic C-H animation.
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| Hazard Information | Back Directory | [Uses]
Catalyst used for:
- Asymmetric anti-Mannich reactions
- Coupling reactions
- Ring-opening and Diels-Alder reactions
- Allylic C-H oxidation of terminal alkenes
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Energy Chemical
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http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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