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ChemicalBook--->CAS DataBase List--->164858-78-0

164858-78-0

164858-78-0 Structure

164858-78-0 Structure
IdentificationBack Directory
[Name]

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
[CAS]

164858-78-0
[Synonyms]

(R)-(+)-2-[2-(Diphenylphosphino
(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazol
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE
(R)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYL-OXAZOLE
(R)-(+)-2-[2-(Diphenylphosphino)Phenyl]-4-(1-Methyl)-4,5-Dihydrooxazole
(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
(4R)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(4R)-(+)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98%
(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN)
(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98%
(4R)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.
[Molecular Formula]

C24H24NOP
[MDL Number]

MFCD02684553
[MOL File]

164858-78-0.mol
[Molecular Weight]

373.43
Chemical PropertiesBack Directory
[Appearance]

White crystalline powder
[Melting point ]

85-90 °C
[alpha ]

+44° (c 1.4, CHCl3)
[Boiling point ]

492.7±28.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[pka]

4.31±0.70(Predicted)
[color ]

white
[optical activity]

[α]20/D +48±3°, c = 1.4% in chloroform
[Sensitive ]

air sensitive
[BRN ]

8156604
[InChIKey]

OUQSAXROROGQEE-QFIPXVFZSA-N
[CAS DataBase Reference]

164858-78-0
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

37/39-26-24/25
[WGK Germany ]

3
[F ]

10-23
[HS Code ]

29349990
Questions And AnswerBack Directory
[Reaction]

Chiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
Decarboxylative allylic alkylation. Reactions of 164858-78-0
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