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ChemicalBook--->CAS DataBase List--->157488-65-8

157488-65-8

157488-65-8 Structure

157488-65-8 Structure
IdentificationBack Directory
[Name]

(R)-MONOPHOS
[CAS]

157488-65-8
[Synonyms]

(R)-MONOPHOS
(S)-MONOPHOS
97% (R)-MONOPHOS
3,4-a']dinaphthalen
3,4-a']dinaphthalen-4-yl)Morpholine
3,4-a']dinaphthalen-4-yl)piperidine
3,4-a']dinaphthalen-4-yl)dipropylaMine
3,4-a']dinaphthalen-4-yl)dimethylamine
(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)[(1S)-1-phenylethyl]-aMine
3,4-a']dinaphthalen-4-yl)dimethylamine,97% (R)-MONOPHOS
3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(R)-MONOPHOS
-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
R-8,9,10,11,12,13,14,15,Octahydro-3,5-dioxa-4-phosphacyclohepta[2,1-a
(R)-N,N-DiMethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
(11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(R)-(-)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
(11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.
(R)-(-)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE
(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diMethylaMine 97%
(R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2.1-d:1'.2'-f][1.3.2]dioxaphosphepine(R)-monophos]
(R)-()-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]di-naphthalen-4-yl)dimethylamine,(R)-Monophos
(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS
[Molecular Formula]

C22H18NO2P
[MDL Number]

MFCD03426988
[MOL File]

157488-65-8.mol
[Molecular Weight]

359.36
Chemical PropertiesBack Directory
[Melting point ]

190 °C (dec.)
[alpha ]

-583° (c 0.06, CHCl3)
[Boiling point ]

548.7±33.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[pka]

1.22±0.20(Predicted)
[color ]

white
[Sensitive ]

air sensitive
[InChIKey]

QCHAVHXSBZARBO-UHFFFAOYSA-N
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

2934.99.4400
Questions And AnswerBack Directory
[Reaction]

  1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
  2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
  3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
  4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
  5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.
Reactions of 157488-65-8
Hazard InformationBack Directory
[Uses]

Spectrum DetailBack Directory
[Spectrum Detail]

(R)-MONOPHOS(157488-65-8)1HNMR
(R)-MONOPHOS(157488-65-8)31PNMR
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