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ChemicalBook--->CAS DataBase List--->15681-48-8

15681-48-8

15681-48-8 Structure

15681-48-8 Structure
IdentificationBack Directory
[Name]

Dimethylcopperlithium
[CAS]

15681-48-8
[Synonyms]

Dimethylcopperlithium
[Molecular Formula]

C2H6CuLi
[MOL File]

15681-48-8.mol
[Molecular Weight]

100.556
Chemical PropertiesBack Directory
[solubility ]

sol THF, Et2O
Hazard InformationBack Directory
[Uses]

Dimethylcopperlithium is used as a methylating reagent; undergoes conjugate addition reactions, 1,2-addition reactions, substitution reactions with alkyl, vinyl, and allyl substrates, carbocupration of alkynes, and reduction of carbon-heteroatom bonds.
[Preparation]

Dimethylcopperlithium free of LiI can be prepared from isolated Methylcopper, and the reagent can also be prepared in the presence of complexing agents from CuI.SBu2, Copper(I) Iodide-Tributylphosphine, or CuBr.SMe2. Polymer-supported Me2CuLi is also available.
[storage]

Dimethylcopperlithium is air- and moisture-sensitive; handle under inert atmosphere in a fume hood.
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