| Identification | Back Directory | [Name]
FERBAM | [CAS]
14484-64-1 | [Synonyms]
f40
F 40
ferban
FERBAM
FERBERK
FERMATE
cormate
ferbeck
ferbame
hokmate
niacide
liromate
Fuklazin
ferbam50
Ferradow
Aafertis
HEXAFERB
KNOCKMATE
fermocide
fermacide
ent14,689
Ferbam 50
trifungol
trimanzone
VANCIDE(R)
FERMATE(R)
FERBERK(R)
Aaferzimag
FERRADOW(R)
IRON ME2DTC
karbamblack
vancidefe95
Ferbam (ISO)
Karbam Black
CARBAMATE(R)
fuklasinultra
Fuklasin Ultra
staufferferbam
fluororesin 40
Stauffer ferbam
FERBAM STANDARD
ferbam,ironsalt
KARBAM BLACK(R)
FERBAM GRANUFLO
bercemafertam50
Bercema Fertam 50
Ferbam, Iron salt
ferbam (bsi,iso,jmaf)
fermateferbamfungicide
ferricdimethyldithioate
sup’r-floferbamflowable
Fermate Ferbam fungicide
irondimethyldithiocarbamate
eisendimethyldithiocarbamat
Iron dimethyldithiocarbamate
FERRIC DIMETHYLDITHIOCARBAMATE
IRON(III) DIMETHYLDITHIOCARBAMATE
irontris(dimethyldithiocarbamate)
tris(dimethyldithiocarbamato)-iro
Tris(dimethyldithiocarbamato)iron
dimethyldithio-carbamicaciironsalt
dimethyldithiocarbamicacid,ironsalt
Iron, tris(dimethyldithiocarbamato)-
ferricdimethyldithiocarbamate(ferbam)
tris(N,N-Dimethyldithiocarbamate)iron
dimethyldithio-carbamicaciiron(3+)salt
dimethyl-carbamodithioicaciironcomplex
Dimethyldithiocarbamic acid, iron salt
dimethyldithiocarbamicacid,iron(3+)salt
dimethylcarbamodithioicacid,ironcomplex
DIMETHYLDITHIOCARBAMIC ACID FERRIC SALT
tris(dimethylcarbamodithioate-s,s’)iron
tris(dimethylcarbamodithioato-s,s’)iron
dimethyl-carbamodithioicacidiron(3+)salt
dimethylcarbamodithioicacid,iron(3+)salt
FERBAM TECHNICAL MIXTURE, PESTANAL, (IRO
tris(n,n-dimethyldithiocarbamato)iron(111)
Tris(N,N-dimethyldithiocarbamato)iron(III)
Dimethyldithiocarbamic acid, iron(3+) salt
eisen(iii)-tris(n,n-dimethyldithiocarbamat)
Iron, tris(dimethylcarbamodithioato-S,S’)-,
Carbamic acid, dimethyldithio-, iron(3+) salt
Carbamodithioic acid, dimethyl-, iron(3+) salt
s’)-tris(dimethylcarbamodithioato-(oc-6-11)-iro
ferbam (ISO) iron tris(dimethyldithiocarbamate)
Tris(dimethyldithiocarbamic acid)iron(III) salt
(oc-6-11)-tris(dimethylcarbamodithioato-s,s’)iron
Iron, tris(dimethylcarbamodithioato-S,S')-, (OC-6-11)-
Iron, tris(dimethylcarbamodithioato-.kappa.S,.kappa.S)-, (OC-6-11)-
Dimethyldithiocarbamic Acid Ferric Salt
Ferbam
Ferric Dimethyldithiocarbamate | [EINECS(EC#)]
238-484-2 | [Molecular Formula]
C9H18FeN3S6 | [MDL Number]
MFCD00067269 | [MOL File]
14484-64-1.mol | [Molecular Weight]
416.49 |
| Chemical Properties | Back Directory | [Definition]
A wettable powder containing 76% ferbam. | [Appearance]
Ferbam is a combustible, odorless dark
brown to black powder or granular solid | [Melting point ]
180°C (dec.) | [density ]
0.21[at 20℃] | [vapor pressure ]
2 x 10-11 Pa (est.) | [storage temp. ]
0-6°C | [solubility ]
DMSO (Slightly) | [form ]
solid | [Water Solubility ]
130 mg l-1 (room temperature) | [color ]
Black | [Stability:]
Stable. Incompatible with strong oxidants. | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Merck ]
14,4013 | [Exposure limits]
NIOSH 10 mg/m3, IDLH 800 mg/m3; OSHA PEL: TWA 15 mg/m3; ACGIH TLV: TWA 10 mg/m3.
| [InChIKey]
WHDGWKAJBYRJJL-UHFFFAOYSA-K | [LogP]
-1.597 at 20℃ | [CAS DataBase Reference]
14484-64-1 | [IARC]
3 (Vol. 12, Sup 7) 1987 | [EPA Substance Registry System]
Ferbam (14484-64-1) |
| Hazard Information | Back Directory | [Chemical Properties]
odourless black solid | [Uses]
Fungicide. | [General Description]
Dark brown to black odorless solid. Used as a fungicide. | [Air & Water Reactions]
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. | [Reactivity Profile]
FERBAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. | [Hazard]
Irritant to eyes and mucous membranes.
Questionable carcinogen. | [Potential Exposure]
A dithiocarbamate. A potential danger
to those involved in the production, formulation and application of this dithiocarbamate; used as a fungicide, rubber
accelerator, and plastics prodegradant. Some dithiocarbamates have been used as rubber components | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit | [Shipping]
UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous
materials. UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required | [Incompatibilities]
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides. Heat alkalies (lime); moisture can cause decomposition. Decomposes on prolonged
storage. Dithiocarbamate esters are combustible. They react
violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of Dithiocarbamate compounds, including carbon
disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates
slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions
are accelerated by acids. Flammable gases are generated by
the combination of dithiocarbamate with aldehydes, nitrides,
and hydrides. Dithiocarbamate are incompatible with acids,
peroxides, and acid halides. | [Description]
Ferbam is a combustible, odorless dark brownto black powder or granular solid. Molecularweight = 416.51; Freezing/Melting point = .180 C(decomposes). Hazard Identification (based on NFPA-704M Rating System): Health 2, Flammability 1, Reactivity 0.Practically insoluble in water; solubility = 0.01%. | [Waste Disposal]
Ferbam is hydrolyzed by
alkali and is unstable to moisture, lime and heat. Ferbam
can be incinerated. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and
pesticide containers. Must be disposed properly by following package label directions or by contacting your local or
federal environmental control agency, or by contacting
your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant
(≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal | [Health Hazard]
Ferbam is an irritant of the eyes
and respiratory tract; in animals it causes
central nervous system depression, and it is
expected that severe exposure will cause the
same effect in humans. | [Flammability and Explosibility]
Notclassified | [Agricultural Uses]
Fungicide: Registered for use in the U.S. and Canada. Not approved
for use in EU countries. A dimethyl-dithiocarbamate fungicide. It is widely used, together with other fungicides, to
control Postbloom Fruit Drop (PFD) on citrus crops, and as
a foliar protectant against scab, rust, mold and many fungus
disease on fruits, vegetables, melons and ornamentals. It is
registered in several states for use on currents and gooseberries to control leaf spot disease, and on apple, crabapple, hawthorn and quince to control cedar-apple rust disease. It is used
to control rust disease on shrubs and ornamentals. | [Trade name]
AI3-14689®; AAFERTIS®; APPLE DUST
No. 1®[C]; BERCEMA FERTAM 50®; CASWELL No.
458®; FERBAM 50®; FERBECK®; FERMATE FERBAM
FUNGICIDE®[C]; FERMOCIDE®; FERRADOUR®;
FERRADOW®; FUKLASIN ULTRA®; HEXAFERB®;
HOKMATE®; KARBAM BLACK®; KARBAM
CARBAMATE®; KNOCKMATE®; NIACIDE®;
STAUFFER FERBAM®; SUP’R-FLO FERBAM
FLOWABLE®; TRICARBAMIX®[C]; TRIFUNGOL®;
VANCIDE FE95®[C] | [Environmental Fate]
Plant. Decomposes in plants to ethylene thiourea, ethylene thiuram monosul?de, ethylene thiuram disul?de and sulfur (Hartley and Kidd, 1987).
Chemical/Physical. Hydrolyzes in acidic media releasing carbon disul?de. Decomposes in water forming ethylene thiourea (Hartley and Kidd, 1987).
Decomposes >180°C (Windholz et al., 1983) emitting toxic fumes of nitrogen and sulfur oxides (Lewis, 1990; Sax and Lewis, 1987).
| [Metabolic pathway]
Ferbam generates dimethyldithiocarbamic acid by being cleaved in acidic
conditions and in biological media. The acid is conjugated with glucose
and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic
acid is further degraded to dimethylamine and CS2. An
extensive review of the properties of the dithiocarbamate pesticides was
published by the World Health Organisation (WHO, 1988) from which
much of the following information is taken. | [storage]
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Ferbam is incompatible with strong oxidizers (suchas chlorine, bromine, and fluorine). Store in tightly closedcontainers in a cool, well-ventilated area away from oxidizers, strong bases and from heat and moisture. Ferbam candecompose upon long-term storage. | [Degradation]
Ferbam is hydrolysed in acidic media forming dimethyldithiocarbamic
acid (2) that in turn decomposes to liberate carbon disulfide (PM) (see
Scheme 1). |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N | [Risk Statements ]
36/37/38-50/53 | [Safety Statements ]
26-36/37/39-61-60 | [RIDADR ]
UN3077 9/PG 3 | [RTECS ]
NO8750000 | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29302000 | [Safety Profile]
Poison by
intraperitoneal route. Moderately toxic by
ingestion. Experimental teratogenic and
reproductive effects. Questionable
carcinogen with experimental carcinogenic
and tumorigenic data. Mutation data
reported. A fungicide. When heated to
decomposition it emits very toxic fumes of NOx and SOx. See also CARBAiMATES. | [Hazardous Substances Data]
14484-64-1(Hazardous Substances Data) | [Toxicity]
LD50 in male mice, rats (mg/kg): 3000, 2700 i.p. (Hodge) | [IDLA]
800 mg/m3 |
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