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ChemicalBook--->CAS DataBase List--->13686-28-7

13686-28-7

13686-28-7 Structure

13686-28-7 Structure
IdentificationBack Directory
[Name]

Thiosulfuric acid
[CAS]

13686-28-7
[Synonyms]

Thiosulfuric acid
sulfurothioic O-acid
Thiosulfuric acid (H2S2O3) (9CI)
[Molecular Formula]

H2O3S2
[MOL File]

13686-28-7.mol
[Molecular Weight]

114.13
Hazard InformationBack Directory
[Physical properties]

Thiosulfuric acid is a sulfur oxoacid. The free acid cannot be prepared by acidifying thiosulfate salts as the acid readily decomposes in water. Anhydrous methods of producing the acid are:
H2S+ SO3→H2S2O3·nEt2O (in diethyl ether at 78°C)
Na2S2O3+2HCl/2NaCl+H2S2O3·2Et2O
(in diethyl ether at 78°C)
HSO3Cl+H2S→HCl+H2S2O3 (low temperature)
The anhydrous acid also decomposes below 0°C:
H2S2O3→H2S+ SO3
There is another isomeric form, a white crystalline adduct of hydrogen sulfide and sulfur trioxide, H2S·SO3, which can also be prepared at low temperature.
[Definition]

ChEBI: Sulfurothioic S-acid is a thiosulfuric acid. It has a role as a mouse metabolite. It is a conjugate acid of a hydroxidodioxidosulfidosulfate(1-). It is a tautomer of a sulfurothioic O-acid.
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