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ChemicalBook--->CAS DataBase List--->13478-18-7

13478-18-7

13478-18-7 Structure

13478-18-7 Structure
IdentificationBack Directory
[Name]

MOLYBDENUM (III) CHLORIDE
[CAS]

13478-18-7
[Synonyms]

Einecs 236-775-9
ybdenum(III) chL
MOLYBDENUM CHLORIDE
trichloromolybdenum
MOLYBDENUM (III) CHL
MOLYBDENUM TRICHLORIDE
MOLYBDENUM (III) CHLORIDE
molybdenumchloride(mocl3)
MOLYBDENUM CHLORIDE (III), 99%
MOLYBDENUM(III) CHLORIDE: 99.5%
Molybdenum(III)chloride(99.5%-Mo)
Molybdenum(III)chloride,99.5%(metalsbasis)
Molybdenum(III) chloride, 99.5% trace metals basis
MolybdenuM(III) chloride 99.95% trace Metals basis
MOLYBDENUM (III) CHLORIDE, 99%MOLYBDENUM (III) CHLORIDE, 99%MOLYBDENUM (III) CHLORIDE, 99%
[EINECS(EC#)]

236-775-9
[Molecular Formula]

Cl3Mo
[MDL Number]

MFCD00014214
[MOL File]

13478-18-7.mol
[Molecular Weight]

202.3
Chemical PropertiesBack Directory
[Melting point ]

1027°C
[density ]

3.58 g/mL at 25 °C(lit.)
[solubility ]

H2O: insoluble(lit.)
[form ]

Powder
[color ]

Dark red
[Specific Gravity]

3.59
[Water Solubility ]

Soluble in nitric acid and sulfuric acid. Insoluble in water and dilute hydrochloric acid. Slightly soluble in ethanol and diethyl ether.
[Crystal Structure]

AlCl3 type
[Sensitive ]

Air & Moisture Sensitive
[crystal system]

Monoclinic
[Space group]

C2/m
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.60980.97570.630190108.06900.3564
[Exposure limits]

ACGIH: TWA 0.5 mg/m3; TWA 10 mg/m3; TWA 3 mg/m3
NIOSH: IDLH 1000 mg/m3; IDLH 5000 mg/m3
[CAS DataBase Reference]

13478-18-7
[EPA Substance Registry System]

Molybdenum chloride (MoCl3) (13478-18-7)
Hazard InformationBack Directory
[Chemical Properties]

-100 mesh with 99.5% purity; purple crystal(s) [STR93] [CER91]
[Uses]

Molybdenum(III) chloride reacts with tetrahydrothiophene to form complexes, which catalyze the polymerization and cyclotrimerization of alkynes.
[Definition]

ChEBI:Molybdenum trichloride is a molybdenum halide.
[Purification Methods]

Boil it with 12M HCl, wash it with absolute EtOH and dry it in a vacuum desiccator. It is a brown-red powder soluble in H2O, EtOH or Et2O and gives a blue solution in conc H2SO4. [Hein & Herzog Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1404 1965.]
[reaction suitability]

reagent type: catalyst
core: molybdenum
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37/39
[RIDADR ]

UN3260
[WGK Germany ]

3
[RTECS ]

QA4681400
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
Spectrum DetailBack Directory
[Spectrum Detail]

MOLYBDENUM (III) CHLORIDE(13478-18-7)IR
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