Identification | Back Directory | [Name]
PYRAZOPHOS | [CAS]
13457-18-6 | [Synonyms]
AFUGAN Curamil hoe2873 Missile Siganex HOE 2873 carbonyl- AFUGAN(R) PYRAZOFOS HOE 02873 Afugan(TM) ophosphate NSC 232671 PYRAZOPHOS Hoechst 2873 Afugan powder Pyrazophos 0.2 PYRAZOPHOS STANDARD PYRAZOPHOS, 100MG, NEAT pyrazophos (bsi,iso)afugan PYRAZOPHOS PESTANAL, 250 MG Pyrazophos Solution, 100ppm Pyrazophos @100 μg/mL in MeOH Pyrazophos 100mg [13457-18-6] Pyrazophos powder(content>55%) l)pyrazolo(1,5-a)pyrimidin-2-ol Pyrazophos emulsion(content>15%) Pyrazophos@1000 μg/mL in Acetone Pyrazophos Solution in Methanol, 100μg/mL phosphorothioicacid,o,o-diethylester,o-esterwith(6-ethoxycarbonyl-5-methy Diethyl 6-carbethoxy-5-methylpyrazolo[1,5-a]pyrimidin-2-yl phosphorothioate pyrazolo-(1,5a)pyrimidine,2-(o,o-diethyl-thionophosphoryl)-5-methyl-6-ethoxy 2-(o,o-diethyl-thionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5a)pyrimi ethyl2-((diethoxyphosphinothioyl)oxy)-5-methylpyrazolo(1,5-a)pyrimidine-6-ca o,o-diethyl-o-(5-methyl-6-ethoxy-carbonyl-pyrazolo(1.5-a)pyrimid-2-yl)-thion 2-(O,O-Diethyl thionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo(1,5a)pyrimidin 2-(O,O-Diethyl-thionophosphoryl)-5-methyl-6-carbethoxy-pyrazolo-(1,5-a)pyrimidine ETHYL-2-DIETHOXYPHOSPHINOTHIOYLOXY-5-METHYLPYRAZOLO[1,5-A]-PYRIMIDINE-6-CARBOXYLATE Pyrazolo(1,5a)pyrimidine, 2-(O,O-diethyl thionophosphoryl)-5-methyl-6-ethoxycarbonyl- O,O-Diethyl-o-[5-methyl-6-ethoxycarbonylpyrazole [1,5a] pyrimid-2-yl] thionophosphate Ethyl 2-[(diethoxyphosphorothioyl)oxy]-5-methylpyrazolo[1,5-a]pyrimidine-6-carboxylate O,O-Diethyl-O-(5-methyl-6-ethoxy-carbonyl-pyrazolo(1.5-a)pyrimid-2-yl)-thionophosphate O,O-diethyl-O-(6-ethoxyearbonyl-5-methylpyrazolo[1,5α] pyrimidin-2-yl) thionophosphate O,O-DIETHYL-O-6-ETHOXYCARBONYL-5-METHYL-PYRAZOLO [1,5-A]PYRIMIDIN-2-YL-PHOSPHOROTHIONATE 0,0-Diethyl ester-0-6-ethoxycarbonyl-5-methyl)-pirazol-(1,5-pyrilidin-2-ol)-thiophosphoric acid pyrazolo[1,5-a]pyrimidine-6-carboxylicacid,2-[(diethoxyphosphinothioyl)oxy]-5-methyl-,ethylester Pyrazolo[1,5-a]pyrimidine-6-carboxylic acid, 2-[(diethoxyphosphinothioyl)oxy]-5-methyl-, ethyl ester phosphorothioicacid,o,o-diethylester,o-esterwith(6-ethoxycarbonyl-5-methyl)pyrazolo(1,5-a)pyrimidin-2-ol pyrazophos (ISO) O,O-diethyl O-(6-ethoxycarbonyl-5-methylpyrazolo[2,3-a]pyrimidin-2-yl) phosphorothioate Ethyl 2-hydroxy-5-methylpyrazolo(1,5-a)pyrimidine-6-carboxylate O-ester of O,O-diethylphosphorothioic acid Phosphorothioic acid, O,O-diethyl ester O-ester with (6-ethoxycarbonyl-5-methyl)pyrazolo(1,5-pyrimidin-2-ol) phosphorothioicacid,o,o-diethylester,esterwithethyl-2-hydroxy-5-methylpyrazolo[1,5-a]pyrimidine-6-carboxylate Phosphorothioic acid, O,O-diethyl ester, O-ester with (6-ethoxycarbonyl-5-methyl)pyrazolo(1,5-a)pyrimidin-2-ol Pyrazolo[1,5-a]pyrimidine-6-carboxylic acid, 2-hydroxy-5-methyl-, ethyl ester, O-ester with O,O-diethyl phosphorothioate | [EINECS(EC#)]
236-656-1 | [Molecular Formula]
C14H20N3O5PS | [MDL Number]
MFCD00055494 | [MOL File]
13457-18-6.mol | [Molecular Weight]
373.36 |
Chemical Properties | Back Directory | [Melting point ]
51℃ | [density ]
1.38±0.1 g/cm3(Predicted) | [vapor pressure ]
2.2 x 10-4 Pa (50 °C) | [storage temp. ]
APPROX 4°C
| [form ]
neat | [pka]
-1.37±0.40(Predicted) | [Water Solubility ]
4.2 mg l-1 (25 °C) | [Merck ]
13,8052 | [BRN ]
577209 | [EPA Substance Registry System]
Pyrazophos (13457-18-6) |
Hazard Information | Back Directory | [Uses]
Fungicide. | [Uses]
Pyrazophos is a systemic fungicide that provides both protective
and curative control of various fungal diseases such as powdery mildew
(Podosphaera) on apples, stone fruits, bush fruits and strawberries,
Erysiphe in cucurbits and tomatoes, Uncinula on vines and leaf blotch
(Rhynchosporium) in cereals. | [Definition]
ChEBI: A member of the class of pyrazolopyrimidines that is the ethyl ester of 2-[(diethoxyphosphorothioyl)oxy]-5-methylpyrazolo[1,5-a]pyrimidine-6-carboxylic acid. A fungicide used to control Erysiphe, Helminthosporium and
ital>Rhynchospium in cereals. | [Metabolic pathway]
Limited information is available to describe the degradation and metabolic
fate of pyrazophos. Hydrolytic cleavage of the P-O-pyrazolopyrimidine
linkage is the primary metabolic pathway. Oxidative
desulfuration of pyrazophos to pyrazophos-oxon is only a minor
pathway, observed in the plant metabolism study (Scheme 1). | [Metabolism]
Its mode of action is believed to be the inhibition of
melanin biosynthesis and the development of appressoria
by fungal conidia. Formulation is available as emulsifiable
concentrate (EC: 30%). Application rates on Oidium spp.
are in the range of 15–30 g a.i./hl. | [Degradation]
Pyrazophos (1) is hydrolysed in acidic or alkaline solution (PM). |
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