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ChemicalBook--->CAS DataBase List--->1300746-79-5

1300746-79-5

1300746-79-5 Structure

1300746-79-5 Structure
IdentificationBack Directory
[Name]

(1,10-Phenanthroline)(trifluoroMethyl)copper(I), 95%
[CAS]

1300746-79-5
[Synonyms]

Trifluoromethylator
(1,10-Phenanthroline)(trifluoromethyl)copper
(1,10-Phenanthroline)(trifluoroMethyl)copper(I), 95%
TrifluoroMethyl(1,10-phenanthroline)copper(I), 95% TrifluoroMethylator
Trifluoromethyl(1,10-phenanthroline)copper(I), 95% Trifluoromethylator(R)
[Molecular Formula]

C13H8CuF3N2
[MDL Number]

MFCD19690901
[MOL File]

1300746-79-5.mol
[Molecular Weight]

312.757
Chemical PropertiesBack Directory
[Melting point ]

>230°C (dec.)
[storage temp. ]

2-8°C
[form ]

Solid
[color ]

Orange
[Sensitive ]

air sensitive, moisture sensitive, store cold
[InChIKey]

CUQZQRIIFNWQSJ-UHFFFAOYSA-N
[CAS DataBase Reference]

1300746-79-5
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

21/22-36/38
[Safety Statements ]

26-36/37
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

Reagent used for the perfluoromethylation of arenes and aryl bromides and iodides.
Catalyst used in the copper-mediated perfluoroalkylation of heteroaryl bromides. Reactions of 1300746-79-5
Hazard InformationBack Directory
[Uses]

(1,10-Phenanthroline)(trifluoromethyl)copper is used as a catalyst in the oxtidative trifluoromethylation of heteroarenes.
[Uses]

New versatile reagent for the trifluoromethylation of various aryls/heteroaryls.
[General Description]

(1,10-Phenanthroline)(trifluoromethyl)copper(I) [(Phen)Cu-CF3] can be prepared by treating [CuOt-Bu]4 with 1,10-phenanthroline, followed by the addition of (trifluoromethyl)trimethylsilane (CF3TMS). It is an easily handled, thermally stable, single-component reagent.
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