| Identification | Back Directory | [Name]
Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0) | [CAS]
1260119-00-3 | [Synonyms]
NH2-UiO-66
UIO-66-NH2
NH2-UIO-66(Zr)
UiO-66-NH2(Zr)
MOF:UiO-66(Zr)-NH2
Zirconium aminobenzenedicarboxylate MOF
ZIRCONIUMAMINOBENZENEDICARBOXYLATEMOF(UIO-66-BDC-NH2,BDC-NH2:ZR=0.9-1.0)
UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0,Zirconium aminobenzenedicarboxylate MOF | [Molecular Formula]
C48H30N6O32Zr6 | [MOL File]
1260119-00-3.mol | [Molecular Weight]
1750.12 |
| Chemical Properties | Back Directory | [form ]
solid | [color ]
Yellow | [InChI]
InChI=1S/6C8H7NO4.8O.6Zr/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;/q;;;;;;4*-2;4*-1;6*+4/p-12 | [InChIKey]
SGCQKKMGUIJGFK-UHFFFAOYSA-B |
| Questions And Answer | Back Directory | [Uses]
Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0) Useful MOF for adsorption of CO2 applications
Catalyst MOF used in the conversion of toxic agents to non-toxic products
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| Hazard Information | Back Directory | [Definition]
UiO-66-NH2(Zr), a zirconium-based functional metal–organic framework (MOF), was post synthetically modified via Schiff base reaction between aldehyde groups in glutaraldehyde and amino groups in UiO-66-NH2 and CO2-preabsorbed polyethyleneimine (PEI). Compared with pristine UiO-66-NH2, the PEIC@UiO adsorbents have reduced specific surface area (7–150 m2/g) but maintained the same crystal structure. Notably, the PEIC96@UiO adsorbent exhibited significantly improved CO2/N2 adsorption selectivity (48 vs 25) and higher CO2 adsorption capacity. The adsorbent also displayed moderate desorption energy (68 kJ/mol CO2), superior moisture endurance, and recyclability[1].
| [References]
[1] Junjie Zhu. “Polyethyleneimine-Modified UiO-66-NH2(Zr) Metal–Organic Frameworks: Preparation and Enhanced CO2 Selective Adsorption.” ACS Omega 4 2 (2019): 3188–3197. |
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| Company Name: |
Chemsoon Co., Ltd Gold
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021-51987688-803 |
| Website: |
http://www.chemsoon.com.cn |
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