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ChemicalBook--->CAS DataBase List--->12279-09-3

12279-09-3

12279-09-3 Structure

12279-09-3 Structure
IdentificationBack Directory
[Name]

Chlorobis(cyclooctene)rhodium(I) dimer
[CAS]

12279-09-3
[Synonyms]

[Rh(coe)2Cl]2
Chlorobis(cyclooctene)rhodium(I)
CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
Chlorobis(cyclooctene)rhodium(I)dimere
CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER
Chlorobis(cyclooctene)rhodiuM(I),diMer 98%
Chlorobis(cyclooctene)rhodium(I) dimer,98%
Chlorobis(cyclooctene)rhodium(I)dimer,min.98%
Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
Chlorobis(cyclooctene)rhodiuM(I) diMer, 98% 100MG
[EINECS(EC#)]

623-340-7
[Molecular Formula]

C32H56Cl2Rh2
[MDL Number]

MFCD00013287
[MOL File]

12279-09-3.mol
[Molecular Weight]

717.5
Chemical PropertiesBack Directory
[Appearance]

orange-brown powder
[Melting point ]

190 °C (dec.)(lit.)
[storage temp. ]

Freezer
[form ]

crystal
[color ]

orange to red
[Sensitive ]

air sensitive, store cold
[CAS DataBase Reference]

12279-09-3
Hazard InformationBack Directory
[Chemical Properties]

orange-brown powder
[Uses]

Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
  • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
  • In direct C-arylation of N-unprotected indoles and pyrroles.
  • In the carboxylation of arenes via C-H bond activation.

Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
Spectrum DetailBack Directory
[Spectrum Detail]

Chlorobis(cyclooctene)rhodium(I) dimer(12279-09-3)1HNMR
Chlorobis(cyclooctene)rhodium(I) dimer(12279-09-3)FT-IR
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