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ChemicalBook--->CAS DataBase List--->119692-59-0

119692-59-0

119692-59-0 Structure

119692-59-0 Structure
IdentificationBack Directory
[Name]

4-Hydroxybutyl acrylate glycidyl ether
[CAS]

119692-59-0
[Synonyms]

4-(2,3-EPOXYPROPOXY)BUTYLACRYLATE
4-(Oxiran-2-ylmethoxy)butyl Acrylate
4-Hydroxybutyl acrylate glycidyl ether
4-(oxiran-2-ylmethoxy)butyl prop-2-enoate
2-Propenoic acid, 4-(2-oxiranylmethoxy)butyl ester
4-Hydroxybutyl acrylate glycidyl ether ISO 9001:2015 REACH
[Molecular Formula]

C10H16O4
[MDL Number]

MFCD30474906
[MOL File]

119692-59-0.mol
[Molecular Weight]

200.23
Chemical PropertiesBack Directory
[Boiling point ]

287.5±20.0 °C(Predicted)
[density ]

1.077±0.06 g/cm3(Predicted)
[InChI]

InChI=1S/C10H16O4/c1-2-10(11)13-6-4-3-5-12-7-9-8-14-9/h2,9H,1,3-8H2
[InChIKey]

USWANRSZMQLWTG-UHFFFAOYSA-N
[SMILES]

C(OCCCCOCC1CO1)(=O)C=C
[EPA Substance Registry System]

2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester (119692-59-0)
Hazard InformationBack Directory
[Description]

4-Hydroxybutyl Acryrate Glycidyl Ether with a glycidylether group at the end of a longer alkyl chain, gives excellent scratch resistance due to its high crosslinking ratio and unique flexibility.This copolymer has good acid rain resistance.It is used in Paint and coating materials,UV/EB curable composition.
[Chemical Properties]

4HBAGE has a glycidylether functional group and a double bond group in the molecule.Various vinyl monomers can be copolymerized with 4HBAGE.The co-polymerized polymer with 4HBAGE achieves a higher crosslinking ratio with curing agents.This is because the glycidylether is further away from the copolymer backbone chain.This copolymer has good acid rain resistance.
[Application]

Paint and coating materials (excellent scratch resistance, mechanical properties, and chemical properties)
Powder coatings
UV/EB curable composition.
Epoxy acrylate
Adhesives
[Synthesis]

The flask was charged with 144 g of 4-hydroxybutyl acrylate and 0.7 g of boron trifluoride ether complex as a catalyst, heated to 55 ° C., and then 92.5 g of epichlorohydrin was added dropwise over 2 hours with stirring. After completion of the dropwise addition, analysis by gas chromatography revealed that the conversion rate of 4-hydroxybutyl acrylate was about 70%, and most of it was converted to a chloroether form.
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